30 Jun 2025
LED, Photodiode, Solar Cell, and Semiconductor Laser
Operating principles and electrical-optical characteristics of four semiconductor optoelectronic devices.
Photons couple most efficiently to a direct-gap semiconductor because electron-hole recombination can conserve crystal momentum without a phonon. The photon energy and free-space wavelength obey
\[h\nu=\frac{hc}{\lambda}.\]
The editable source is optoelectronic-characteristics.tex.
Light-emitting diode
Forward bias injects electrons and holes into an active direct-gap region. Their radiative recombination emits photons with energy concentrated near $E_g$:
\[\lambda\simeq\frac{hc}{E_g}, \qquad \lambda(\mu\mathrm m)\simeq\frac{1.240}{E_g(\mathrm{eV})}.\]The electrical characteristic is diode-like. Above its knee, emitted optical power is approximately proportional to forward current until heating, non-radiative recombination, or efficiency droop becomes important. The forward voltage is of order $E_g/q$ but also contains junction, series-resistance, and temperature contributions; it is not exactly $E_g/q$.
Photodiode
A reverse-biased photodiode absorbs photons with $h\nu\ge E_g$. Electron-hole pairs created in or close to the depletion region are separated by its electric field, producing a reverse photocurrent. With forward diode current defined positive,
\[\boxed{I=I_S\!\left(e^{V/(\eta V_T)}-1\right)-I_{ph}}, \qquad I_{ph}=\mathcal R P_{opt}.\]$\mathcal R$ is responsivity in $\mathrm{A\,W^{-1}}$. If each collected photon produces at most one electron and the external quantum efficiency is $\eta_q$,
\[\boxed{\mathcal R=\eta_q\frac{q}{h\nu} =\eta_q\frac{q\lambda}{hc}}.\]Reverse bias widens the depletion region, lowers junction capacitance, and improves speed, but increases dark-current and breakdown constraints. Below breakdown the reverse current changes nearly linearly with optical power.
Solar cell
A solar cell is a large-area illuminated junction operated without an externally imposed reverse bias. Define delivered current as positive from the cell to the load. Its ideal characteristic is
\[\boxed{I=I_{ph}-I_0\!\left(e^{V/(\eta V_T)}-1\right)}.\]At short circuit,
\[I_{sc}=I(V=0)=I_{ph},\]and at open circuit,
\[\boxed{V_{oc}=\eta V_T\ln\!\left(1+\frac{I_{ph}}{I_0}\right)}.\]The maximum-power point $(V_{mp},I_{mp})$ maximizes $P=VI$. The fill factor and conversion efficiency are
\[FF=\frac{V_{mp}I_{mp}}{V_{oc}I_{sc}}, \qquad \eta_{cell}=\frac{V_{mp}I_{mp}}{P_{in}}.\]Series resistance reduces the high-voltage part of the curve; shunt leakage reduces current near short circuit.
Semiconductor laser
A forward-biased direct-gap double-heterostructure confines electrons, holes, and light to a thin active layer. Sufficient injection creates population inversion. A photon of energy near $E_g$ then stimulates recombination and produces a second photon with the same frequency, phase, direction, and polarization.
Two cleaved or fabricated facets form a Fabry-Perot resonator. Longitudinal modes approximately satisfy
\[2nL=m\lambda,\]where $L$ is cavity length, $n$ refractive index, and $m$ an integer. Lasing begins when modal gain balances internal and mirror losses:
\[\boxed{\Gamma g(N_{th}) =\alpha_i+\frac1{2L}\ln\!\left(\frac1{R_1R_2}\right)}.\]Here $g$ and $\alpha_i$ are in $\mathrm{m^{-1}}$, $\Gamma$ is dimensionless confinement factor, and $R_1,R_2$ are facet power reflectivities. Below threshold the output is mainly spontaneous emission; above threshold $P_{out}$ rises approximately linearly with $I-I_{th}$ and is narrowband, coherent, and directional.
Discussion